Science & STEM

Chemistry Unit 1 Practice Test for AP Students

Moderate25 Questions13 min

AP Chemistry Unit 1 drills atomic structure and properties: particle counts, isotopes/average atomic mass, periodic trends, naming/formulas, and unit-conversion stoichiometry. This 109-question chemistry unit 1 practice test aligns to AP Chemistry Unit 1 expectations. It fits searches for ap chem unit 1 practice test, unit 1 test chemistry, ap chemistry unit 1 practice questions, and ap chemistry unit 1 practice.

25Questions
InstantResults
FreeAlways
DetailedExplanations
Take the Quiz
Choose quiz length
1The atomic number of an element equals the number of protons in its nucleus.

True / False

2How many protons are in a neutral sodium (Na) atom?
3Prefixes such as di- and tri- are typically used when naming ionic compounds.

True / False

4How many neutrons are in a chlorine-35 atom (\u00b3\u2075Cl)?
5Ionization energy increases down a group because valence electrons are farther from the nucleus.

True / False

6What is the correct formula for magnesium nitrate?
7Which set of coefficients balances the equation Al + O\u2082 \u2192 Al\u2082O\u2083?
8When calculating average atomic mass from isotopes, the final value should fall between the masses of the isotopes listed.

True / False

9What is the name of N\u2082O\u2085?
10Element X has two isotopes: 10.01 amu (19.9%) and 11.01 amu (80.1%). What is the average atomic mass of X?
11Arrange the standard stoichiometry workflow in the correct order (starting from a given mass of a reactant and ending with a requested mass of a product).

Put in order

1Balance the chemical equation
2Convert moles of product to mass of product
3Convert the given mass to moles
4Use the mole ratio from coefficients to find moles of product
12A student notices that atomic radius decreases from Na to Cl across Period 3. Which explanation best accounts for this trend?
13Select all that apply. Which checks or steps help prevent mistakes when calculating average atomic mass from isotopic data?

Select all that apply

14How many electrons are in an Fe\u00b3\u207a ion?
15Copper’s isotopes are 62.93 amu (69.17%) and 64.93 amu (30.83%). What is copper’s average atomic mass?
16Arrange these elements in order of increasing electronegativity (lowest \u2192 highest): C, N, O, F.

Put in order

1N
2F
3O
4C
17Select all that apply. When a neutral atom becomes a cation, which quantities change?

Select all that apply

18In any balanced chemical equation, the total charge on the reactant side equals the total charge on the product side.

True / False

19How many aluminum atoms are in a 2.70 g sample of Al?
20Arrange the steps to find the number of electrons in the ion \u00b2\u2074Mg\u00b2\u207a in the correct order.

Put in order

1Compute electrons for the neutral atom first
2Adjust electrons based on the 2+ charge
3Identify the atomic number (Z) of Mg
4Set protons equal to Z
21Select all that apply. Which formulas correspond to compounds that must include a Roman numeral in their name?

Select all that apply

22Which species has the smallest ionic radius? (All are isoelectronic with 10 electrons.)
23Arrange these actions in the best order for balancing a chemical equation by inspection.

Put in order

1Write correct formulas for all reactants and products
2Do a final check that coefficients are in the lowest whole-number ratio
3Adjust coefficients to balance one element at a time
4Recount atoms and iterate until all match
5Count atoms of each element on both sides
24For 2Al + 3Cl\u2082 \u2192 2AlCl\u2083, a student reacts 5.40 g Al with 12.0 g Cl\u2082 and obtains 75% yield. What mass of AlCl\u2083 is actually produced?
25Select all that apply. Which dimensional-analysis setups correctly convert 5.00 g Ca to the number of Ca atoms?

Select all that apply

Watch Out

AP Chemistry Unit 1 Setup Errors: Particles, Isotopes, Trends, and Stoichiometry

Most Unit 1 misses come from one wrong label or an unearned assumption. Use these high-frequency failure points as a pre-quiz checklist.

1) Treating the periodic-table atomic mass as a mass number

  • Mistake: Using 35.45 (Cl) as A in neutron counts.
  • Fix: Neutrons require an isotope’s integer mass number (e.g., Cl-35). If only average atomic mass is given, you can’t get a unique neutron count.

2) Losing the sign on ionic charge when counting electrons

  • Mistake: Saying a 2+ ion has 2 more electrons.
  • Fix: Write e− = Z − (positive charge) and e− = Z + (magnitude of negative charge). Put the charge next to Z before calculating.

3) Weighted-average atomic mass with percent-as-whole-number

  • Mistake: Using 75 instead of 0.75, or abundances summing to 100.6% without noticing.
  • Fix: Convert % → fraction, confirm fractions sum to 1.00, and sanity-check: the average must lie between isotope masses.

4) Periodic trend reversals without a causal explanation

  • Mistake: Radius “increases across” or ionization energy “increases down” as memorized slogans.
  • Fix: Tie every trend to Coulombic attraction and shielding: across a period, effective nuclear charge rises; down a group, distance and shielding rise.

5) Naming/formulas: mixing ionic and molecular rule sets

  • Mistake: Using prefixes on ionic compounds or forgetting Roman numerals for variable-charge metals.
  • Fix: Decide compound type first (metal present? polyatomic ion present?), then enforce net charge = 0 for ionic formulas.

6) Stoichiometry before balancing (or without units)

  • Mistake: Building mole ratios from an unbalanced equation or canceling units “by sight.”
  • Fix: Balance first, write every conversion factor with units, and confirm the final unit matches the target (mol, g, particles).
Highlights

Unit 1 Mastery Checklist for AP Chemistry: What Must Be Automatic

AP Chemistry Unit 1 rewards speed on foundational routines. These five skills should feel mechanical before you spend time on multi-step reasoning later in the course.

  1. Separate Z, A, and charge before you compute anything. Start every particle-count problem by writing three labels: Z (protons), A (protons + neutrons), and the ionic charge. Then compute neutrons = A − Z and adjust electrons last, using the charge as the only “change” from the neutral atom.

  2. Run average atomic mass as “sum of (mass × fraction)” with a built-in reasonableness check. Convert each percent abundance to a decimal fraction, multiply each isotope’s mass by its fraction, and add. Immediately verify two conditions: fractions sum to 1.00, and the average lies between the listed isotope masses.

  3. Explain periodic trends using attraction and shielding, not arrows. Across a period, effective nuclear charge increases, so radius decreases and ionization energy/electronegativity generally increase. Down a group, added shells increase distance and shielding, so radius increases and ionization energy generally decreases.

  4. Classify the compound type first; the naming rule follows the type. If it’s ionic, enforce net charge = 0 using the least whole-number ratio, and include Roman numerals for variable-charge metals when required by the name. If it’s molecular (nonmetal–nonmetal), use prefixes to encode atom counts and ensure the second element ends in -ide.

  5. Stoichiometry is dimensional analysis anchored to a balanced equation. Your only legitimate mole ratio comes from coefficients in a balanced chemical equation. Write the pathway (given → desired), then chain conversion factors so units cancel one step at a time; if units don’t cancel cleanly, the setup—not the arithmetic—is wrong.

Links

Authoritative Unit 1 References (College Board, NIST, OpenStax, ACS)

FAQ

AP Chemistry Unit 1 Practice Test FAQ (Atomic Structure & Early Stoichiometry)

What topics should I expect in AP Chemistry Unit 1 (Atomic Structure and Properties)?

Unit 1 typically concentrates on measurable properties tied to atomic-level structure: counting protons/neutrons/electrons (including ions), isotopes and average atomic mass, periodic table organization and trends (radius, ionization energy, electronegativity), and early quantitative chemistry skills like formula writing, equation balancing, and clean dimensional-analysis conversions that feed stoichiometry.

What’s the fastest reliable method to find electrons for an ion?

Write the atomic number Z first (that is the proton count). Then apply the charge as an adjustment to the neutral electron count: neutral has e− = Z; a 2+ cation has e− = Z − 2; a 3− anion has e− = Z + 3. Keeping the sign visible prevents the common “plus means add electrons” error.

How do I avoid mistakes on average atomic mass problems with percent abundance?

Use a two-line template: (1) convert each percent to a fraction by dividing by 100; (2) compute average mass = Σ(mass × fraction). Then run two checks: fractions sum to 1.00, and the final average lies between the isotope masses. If your value falls outside the isotope range, the setup is wrong (usually the percent-to-decimal step).

Which periodic trends are most “AP-useful,” and what justification earns credit?

The most useful trends early on are atomic radius, ionization energy, and electronegativity. A credit-earning justification names the cause: across a period, effective nuclear charge increases (more protons with similar shielding), pulling electrons closer (radius decreases) and making removal harder (ionization energy increases). Down a group, additional shells increase distance and shielding, so radius increases and ionization energy generally decreases.

When should I use prefixes versus charges when writing formulas and names?

Decide compound type before you write anything. For ionic compounds (metal + nonmetal, or any compound containing a polyatomic ion), you do not use prefixes; you balance charges to make net charge zero. For molecular compounds (nonmetal–nonmetal), you use prefixes in the name to reflect atom counts in the formula. If nomenclature is a recurring miss, pair this quiz with the site’s Chemical Nomenclature Quiz - Free Naming Assessment for focused naming/formula drills.

How should I set up Unit 1 stoichiometry so the units “prove” the answer?

Start by balancing the equation, because coefficients create the only valid mole ratios. Next, write a one-line roadmap from the given unit to the target unit (for example: g → mol → mol → g). Build the conversion chain so units cancel stepwise; if the final unit is not exactly what you want (mol, g, particles), stop and rebuild the setup before calculating.

AI-DraftedHuman-Reviewed
Reviewed by
Michael HodgeEdTech Product Lead & Assessment Design SpecialistQuiz Maker
Updated Feb 24, 2026